Di-u-chlorobis[(p-cymene)chloro Ruthenium(II)]

Di-u-chlorobis[(p-cymene)chloro Ruthenium(II)] - Names and Identifiers

Name	Di-mu-chlorobis(p-cymene)chlororuthenium(II)
Synonyms	Dichloro(p-cymene)ruthenium dimer Dichloro(p-cymene)ruthenium(II) dimer DichlorobispcymenechlororutheniumIImin Tetrachlorobis(mu-4-cymene)diruthenium(II) Bis(p-cymene)diruthenium(II) tetrachloride Di--chlorobis[(p-cymene)chlororuthenium(II)] Di-mu-chlorobis(p-cymene)chlororuthenium(II) Di-μ-chlorobis[(p-cymene)chlororuthenium(II)] Di-mu-chlorobis[(p-cymene)chlororuthenium(II)] 1-methyl-4-(1-methylethyl)-, ruthenium complex Di-u-chlorobis[(p-cymene)chloro Ruthenium(II)] (p-Cymene)ruthenium(II) chloride dimer Benzene Di-micron-chlorobis(p-cymene)chlororuthenium(II)
CAS	52462-29-0
EINECS	435-530-5
InChI	InChI=1/2C10H14.4ClH.2Ru/c21-8(2)10-6-4-9(3)5-7-10;;;;;;/h24-8H,1-3H3;41H;;/q;;;;;;2+2/p-4
InChIKey	HDIYUTHATPCURB-UHFFFAOYSA-L

Di-u-chlorobis[(p-cymene)chloro Ruthenium(II)] - Physico-chemical Properties

Molecular Formula	C20H28Cl4Ru2
Molar Mass	612.39
Melting Point	247.0-250.0°C (dec.)(lit.)
Water Solubility	insoluble
Solubility	Chloroform (Sparingly), Ethyl Acetate (Sparingly)
Appearance	Red orange powder
Color	brown
Storage Condition	Sealed in dry,Room Temperature
Sensitive	Sensitive to light
MDL	MFCD00064793
Use	Hydrosilylation Catalysts Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C- H bond activation

Di-u-chlorobis[(p-cymene)chloro Ruthenium(II)] - Risk and Safety

Hazard Symbols	Xn - Harmful
Risk Codes	R22 - Harmful if swallowed R36 - Irritating to the eyes R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Description	S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets.
WGK Germany	2
TSCA	No
HS Code	28439000

Di-u-chlorobis[(p-cymene)chloro Ruthenium(II)] - Introduction

Insoluble in water, soluble in acetone and methanol. Stable to air and humidity.

Last Update：2022-10-16 17:25:52

Di-u-chlorobis[(p-cymene)chloro Ruthenium(II)] - Reference Information

Introduction

Dichlorobis (4-methylisopropylphenyl) ruthenium is a catalyst that can be used in organic chemical reactions and can also be used to prepare new ruthenium (II) complexes.

Uses

Hydrosilylation catalyst
Cyclometallated ruthenium and arylimine and nitrogen-containing heterocyclic rings undergo complexation reaction through C- H bond activation.
Through the reduction reaction of imine and PMHS or by hydrogen reaction, an environmentally friendly amine synthesis method is catalyzed.
A practical and benign primary amine synthesis method using ruthenium to catalyze the reduction of nitriles.
The N-alkylation reaction of amine and sulfonamide catalyzed by ruthenium by hydrogen reaction method.
The reduction reaction of imine and PMHS or hydrogen loan reaction are used for greener amine synthesis catalyst; A mild and practical primary amine synthesis reaction catalyzed by ruthenium for nitrile reduction reaction; N-alkylation reaction catalyzed by ruthenium for amines and sulfonamines through hydrogen loan method; ruthenium ring metallization complex with arylimine and nitrogen-containing heterocycles activated by C- H bonds

Last Update：2024-04-09 19:05:12

Di-u-chlorobis[(p-cymene)chloro Ruthenium(II)]

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